LUCARIO MEGA EVOLUTION

 BLAZIKEN MEGA EVOLUTION 
This pokemon located in the Ist and IInd episode of POKEMON X AND Y.In the first episode ash saw this pokemon's shadow and in the second episode this blaziken mega evolution saves ash and pikachu from falling from the top of a building but still this pokemon is mysterious to ash. 

ASH'S ALL POKEMON

Froakie first appeared in Kalos, Where Dreams and Adventures Begin! where he observed Pikachu shocking Bonnie, Clemont and Ash outside the Lumiose Gym. Froakie protected Pikachu from its own Electro Ball, which had been rebounded by Wobbuffet's Mirror Coat. At the end of the episode, Froakie appeared in front of Sycamore's lab with a Poké Ball and asked Ash to catch it, which Ash did so gladly. Froakie knows Water Pulse, Bubble, Pound, Quick Attack, and Double Team

Fletchling first appeared where it swooped down to take a berry that Bonnie gave to a Dedenne. Afterwards, Froakie challenged it to a battle but Fletchling's speed and strength proved to be too much for Froakie. Froakie was finally able to land a hit on the Tiny Robin Pokémon. Ash threw a Poké Ball at it but the capture was unsuccessful. Froakie continued the battle with Fletchling and landed a hit with Water Pulse. Ash threw another Poké Ball at Fletchling and managed to catch it this time. Fletchling knows Double Team, Peck, Razor Wind, and Steel Wing.

When Squirtle was captured it was part of the Squirtle Squad, a terrorizing group of Squirtles that were causing havoc around Vermillion City. However after gaining respect for Ash, it joined his team and has since become an incredibly competent battler. It has won many Gym and League matches but has since returned to the Squirtle Squad to lead after the team started falling apart. Later, it appears with other Ash's captured Pokémon in Prof. Oak's lab, in the opening scene of BW: Adventures in Unova. Squirtle

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Ash first met Primeape after it, as a Mankey, stole his hat. Determined to get his hat back, Ash chased Primeape and battled with it ending with a capture. Primeape was a Pokémon that went berserk easily and originally didn't follow Ash's commands. However after Ash saved it from a fall in a fighting contest, it gained respect for Ash. After the contest, Ash decided to leave it with a trainer for more training so it could become a P1 Champion. However, it is highly unlikely Ash will return for it given he is easily distracted and forgets the obvious. Later, it appears with other Ash's captured Pokémon in Prof. Oak's lab, in the opening scene of BW: Adventures in Unova. Primape's Moves: Thrash, Scratch, Mega Kick and Seismic Toss. Primeape

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